硫酸與硝酸的混合溶液,取出10ml加入足量bacl2溶液,過濾、洗滌、烘干后得到9.32g的沉淀為硫酸鋇,根據(jù)硫酸根守恒故n(h2so4)=n(baso4)=
9.32g
233g/mol =0.04mol,故原溶液中c(h2so4)=
0.04mol
0.01l =4mol/l;
濾液中氫離子物質(zhì)的量不變,與4.0mol?l-1naoh溶液反應(yīng),用去35ml堿液時恰好完全中和,酸與氫氧化鈉恰好反應(yīng),h+與oh-按物質(zhì)的量之比1:1反應(yīng),故n(hno3)+2(h2so4)=n(naoh),即n(hno3)+2×0.04mol=0.035l×4mol/l,解得n(hno3)=0.06mol,故原溶液中n(hno3)=0.06mol×
100ml
10ml =0.6mol,
答:原混合液中h2so4的物質(zhì)的量濃度為4mol/l,hno3的物質(zhì)的量是0.6mol.